Chemistry in Eclipses

The 14th November 2012 excites students of physics and those interested in astronomy. This is the date of a total eclipse of the sun. The area of totality will pass over northern Australia, from east of Darwin in the Northern Territory to the Cape York Peninsula of Far North Queensland, turning morning into darkness. The rest of Australia will see a partial eclipse.

But why would chemists get excited about a solar eclipse?

The story begins more than 200 years ago ...

Gaps in the Solar Spectrum?

In 1802 an English Chemist, William Hyde Wollaston, was the first person to record the appearance of a number of dark lines in the emission spectrum of light from the sun.

In 1814, German physicist Joseph von Fraunhofer began measuring the wavelengths of over 570 of these lines.

Fingerprinting the Sun

Robert Gustave Kirchhoff and Robert Bunsen, developed a better prism-based spectroscope and observed that the spectral lines emitted by a gas occurred at the same wavelength as the absorption lines observed when incandescent light from Bunsen's burner shone through the same gas heated at the same temperature.

Then Kirchhoff,  proposed the laws of spectroscopy which bear his name:

1. A hot solid object produces light with a continuous spectrum
2. A hot tenuous gas produces light with spectral lines at discrete wavelengths (an emission spectrum)
3. A hot solid object surrounded by a cooler tenuous gas produces light with an almost continuous spectrum with gaps at discrete wavelengths (an absorption spectrum)

A star, like the sun, will create an absorption line spectrum because the continuous spectrum emitted by the dense, opaque gas that makes up most of the star passes through the cooler, transparent atmosphere of the star.

In 1859, Kirchhoff  demonstrated that all pure substances display their own characteristic spectrum, so it is possible to use the spectrum of elements to identify elements in a mixture, just like each person's fingerprints are unique and can be used to identify them. He proposed  that the lines in the solar spectrum are caused by the absorption of light by elements in the solar atmosphere and set out to identify the elements present in our sun.

New Element Discovered

On the 18th August 1868 there was a total solar eclipse. In India, French astronomer Pierre Janssen observed this eclipse using a spectroscope. He recorded a bright yellow line with a wavelength of 587.49 nm in the spectrum of the solar prominences. The same result was also recorded by British astronomer Norman Lockyer. This line could not be due to sodium, because although sodium produces a bright yellow line (actually more than 1), the wavelength of sodium's 'line' is about 589.3 nm. Lockyer proposed that this line was due to a new element which he called helium after the greek word 'helios' meaning 'sun'.

About 10 years later, Scottish chemist William Ramsay isolated helium on earth ...... but that's another story.

References:

http://eclipse.aaq.org.au/

http://www.csiro.au/en/Outcomes/Understanding-the-Universe/Tracking-spacecraft/History-of-total-solar-eclipses.aspx

Further Reading:

Emission Spectra 

Suggested Study Questions:

1. speed of light (m/s) = frequency (s^-1) x wavelength (m)
   If the speed of light is 3 x 10⁸ ms^-1 calculate:
• find the frequency of the 'yellow line' in sodium's spectrum
• find the frequency of the yellow line for the new element found in the solar spectrum
2.  speed of light (m/s) = frequency (s^-1) x wavelength (m)
   If the speed of light is 3 x 10⁸ ms^-1 calculate:
• wavelength of blue light with a frequency of 6.9 x 10¹⁴ s^-1
• wavelength of red light with a frequency of 4.6 x 10¹⁴ s^-1
  
3. The energy of light emitted, E, is Planck's constant,h, multiplied by the speed of light divided by the wavelength of light emitted. Write a mathematical equation to represent this.
4. Use your equation above to calculate
   • energy of the blue light in question 2 above
   • energy of the red light in question 2 above
5. Complete the following generalizations:
   • The longer the wavelength of light, the ___________ energy it has
   • The shorter the frequency of light, the _________ energy it has.
6. Compare the wavelength of the 'yellow line' in sodium's spectrum and the yellow line for the 'new element'. Which element has
   • the longest wavelength
   • the shortest frequency
   • the most energy
7. Describe the difference in the spectrum of light from the sun as seen in a spectroscope compared to the spectrum of light from a fluorescent light as seen in a spectroscope.
8. Explain the differences between the two spectrum in question 7 above.