An aqueous solution is neutral when the concentration of hydrogen ions in solution is equal to the concentration of hydroxide ions in solution:
Neutral solution: [H+(aq)] = [OH-(aq)]
The pH of a solution is a measure of the concentration of hydrogen ions in solution:
pH = -log10[H+(aq)]
For example, an aqueous solution will be neutral if [H+(aq)] = [OH-(aq)] = 10-3 mol L-1
For this solution the pH will be: pH = -log10[H+(aq)] = -log10[10-3] = 3
For example, an aqueous solution will be neutral if [H+(aq)] = [OH-(aq)] = 10-6 mol L-1
For example, an aqueous solution will be neutral if [H+(aq)] = [OH-(aq)] = 10-6 mol L-1
For this solution the pH will be: pH = -log10[H+(aq)] = -log10[10-6] =6
"Neutral" is NOT a pH.
Why do so many (non- Chemists!) believe a solution is neutral if the pH=7 ?
An aqueous solution can have a pH of about 7 IF the temperature of the aqueous solution is about 25°C.
"Neutral" is NOT a pH.
Why do so many (non- Chemists!) believe a solution is neutral if the pH=7 ?
An aqueous solution can have a pH of about 7 IF the temperature of the aqueous solution is about 25°C.
At 25°C, a neutral aqueous solution has pH≈7
Temperature <25°C, a neutral aqueous solution has pH>7
IF the temperature is higher than 25°C, the pH will be less than 7
Temperature >25°C, a neutral aqueous solution has pH<7
The pH of a neutral aqueous solution depends on the temperature of the solution!!!
Suggested Study Questions:
- In an aqueous solution the concentration of hydrogen ions is the same as the concentration of hydroxide ions. Is this solution acidic, basic, or, neutral?
- In an aqueous solution, the concentration of hydrogen ions is 2.7 x 10-6 mol L-1 and the concentration of hydroxide ions is 2.7 x 10-6 mol L-1. Is this solution acidic, basic, or, neutral. Explain your answer.
- The concentration of hydroxide ions in a neutral aqueous solution is 5.8 x 10-6 mol L-1. What is the concentration of hydrogen ions in this solution?
- The concentration of hydrogen ions in a neutral aqueous solution is 7.9 x 10-7 mol L-1 What is the concentration of hydroxide ions in this solution?
- Calculate the pH of the solution in question 4.
- Calculate the pH of the solution in question 3.
- Calculate the pH o the solution in question 2.
- Explain how you would calculate the pH of the solution in question 1, justifying any assumptions you need to make.
- Critically evaluate this statement, "At pH 7 a solution is neutral".
- Chris the Chemist tested the pH of the water in the local pool. Monday was a hot day, about 40°C, and the pH of water was 6.82. That night the temperature dropped dramatically and the next day was a chilly 10°C. When Chris tested the pH of the pool water it was found to be 7.59. Is the pool water acidic, basic, or neutral? Justify your answer.
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