Saturday, May 21, 2016

Stinky Socks and Shmelly Shirts?

Northumbria University researchers have identified six volatile organic compounds on dirty socks and t-shirts which are responsible for the stench of your dirty laundry. Surprisingly, some of these compounds can survive washing in a machine with detergent at 20°C, that is, washing in cold water will not remove all the compounds responsible for the smell.

The researchers wanted to identify the volatile organic compounds from dirty clothes before washing, after washing while still wet, and after drying, to see which compounds are responsible for bad smells and to see if they were eliminated during the washing process.

6 men and 2 women were each given a new pair of socks. Each person was asked to wash their feet and dry them before wearing the socks for at least 10 hours in a specified type of shoe. Each sock was then placed in a separate bag and stored in the dark overnight. 9 men were each given a t-shirt to wear for 2-3 hours while taking part in a soccer match. After the match the t-shirts were bagged separately and refrigerated.

The researchers smelled each item and graded it on a scale of 0 (no bad smell) to 10 (very bad smell).
Then the items were washed in a Tergotometer, a lab machine made up of several miniature washing machines, at 20°C using non-perfumed detergent. Each item was graded for odour after washing while still wet and then again after drying.

Using analytical techniques like gas chromatography, the team identified 6 main volatile organic compounds that contribute to the smell of dirty laundry:
  • butanoic acid (butyric acid); rancid butter odour
  • dimethyl disulfide; onion-like odour
  • dimethyl trisulfide; powerful, unpleasant odour
  • heptan-2-one (2-heptanone); fruity odour like bananas
  • nonan-2-one (2-nonanone); herbaceous odour
  • octan-2-one (2-octanone); apple-like odour
As the concentration of these volatile organic compounds decreased after each washing, the items became less smelly.


Reference:
Chamila J. Denawaka, Ian A. Fowlis, John R. Dean. Source, impact and removal of malodour from soiled clothing. Journal of Chromatography A, 2016; 1438: 216 DOI:10.1016/j.chroma.2016.02.037

Further Reading:
Scientific Method: http://www.ausetute.com.au/scientificm.html
Experimental Design: http://www.ausetute.com.au/experimentd.html
Writing Lab Reports: http://www.ausetute.com.au/labreport.html
Introduction to Functional Groups: http://www.ausetute.com.au/fungroup.html
Naming Alkanoic Acids: http://www.ausetute.com.au/namalkacid.html
Naming Alkanones: http://www.ausetute.com.au/namalkanone.html
2-Dimensional Structural Formula: http://www.ausetute.com.au/structural2D.html
Condensed Structural Formula: http://www.ausetute.com.au/condensedsf.html
Molecular Formula: http://www.ausetute.com.au/molecularformula.html
Molar Mass Calculations: http://www.ausetute.com.au/moledefs.html
Gas Chromatography (GC) : http://www.ausetute.com.au/gc.html

Suggested Study Questions:

  1. What hypothesis was being tested by the researchers in this experiment?
  2. Write an aim for the experiment conducted by the researchers.
  3. Write a method for this experiment as a series of steps.
  4. Tabulate the results of this experiment.
  5. Write a suitable conclusion for this experiment.
  6. Discuss how you could improve this experiment.
  7. Give the 2-dimensional structural formula for each of the following compounds:
    • butanoic acid
    • heptan-2-one (2-heptanone)
    • nonan-2-one (2-nonanone)
    • octan-2-one (2-octanone)
  8. On each structural formula above, circle the functional group and name it.
  9. Classify each of the compounds listed in question 1 on the basis of their functional groups.
  10. Give the molecular formula for each of the following compounds:
    • butanoic acid
    • heptan-2-one (2-heptanone)
    • nonan-2-one (2-nonanone)
    • octan-2-one (2-octanone)
  11. Give the condensed structural formula for each of the following compounds:
    • butanoic acid
    • heptan-2-one (2-heptanone)
    • nonan-2-one (2-nonanone)
    • octan-2-one (2-octanone)
  12. Calculate the molar mass for each of the following compounds:
    • butanoic acid
    • heptan-2-one (2-heptanone)
    • nonan-2-one (2-nonanone)
    • octan-2-one (2-octanone)
  13. Which of the following do you think would have the longest gas chromatography retention time ? Explain your answer.
    • heptan-2-one (2-heptanone)
    • nonan-2-one (2-nonanone)
    • octan-2-one (2-octanone)
  14. Why is gas chromatography (GC) a good choice of analytical technique for this experiment compared to other chromatographic techniques?

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