Showing posts with label graphite. Show all posts
Showing posts with label graphite. Show all posts

Thursday, August 25, 2011

Diamond Planet Discovered

Scientists from Australia, Germany, Italy, the UK and the USA, have detected a companion planet for Pulsar J1719-1438 in our Milky Way, and they believe that this companion planet could be made of diamond. The planet is thought to be small, less than 60,000km in diameter, with a mass slightly greater than that of Jupiter, about 2 x 1027kg.
P1719-1438 and its planet are so close together that the planet is most likely to be a 'stripped-down' white dwarf, that is, one that has lost its outer layers and over 99.9% of its original mass. Based on the planet's orbiting times, the scientists think that this remnant is likely to be made up mostly of carbon and oxygen, while its high density suggests that the material present is crystalline, which leads them to believe that the planet could contain a sizable proportion of diamond.
Graphite can be transformed into diamond under pressures of more than about 4GPa, as is shown in the simplified phase diagram on the right.
On Earth, diamonds can be formed in the mantle where the pressure is great enough to transform carbon sources into diamonds. Diamonds can also form when a meteorite impacts on the Earth because the impact creates a zone of high pressure and temperature in which carbon can be transformed into diamond.


Reference
M. Bailes, S. D. Bates, V. Bhalerao, N. D. R. Bhat, M. Burgay, S. Burke-Spolaor, N. D'Amico, S. Johnston, M. J. Keith, M. Kramer, S. R. Kulkarni, L. Levin, A. G. Lyne, S. Milia, A. Possenti, L. Spitler, B. Stappers, W. van Straten. Transformation of a Star into a Planet in a Millisecond Pulsar Binary. Science, 2011; DOI: 10.1126/science.1208890
Link

Further Reading
Mass Conversions
Density Calculations
Allotropes

Study Questions

  1. Convert 60,000km to a distance in:
    • meters
    • centimeters
    • millimeters
  2. Convert 2 x 1027kg to a mass in
    • grams
    • megagrams
    • gigagrams
  3. What is the approximate radius of of the planet in cm?
  4. What is the volume of the planet in cm3 (assuming the planet is spherical)?
  5. Calculate the approximate density of the newly discovered planet (in g/cm3).
  6. Convert 4GPa to a pressure in:
    • kilopascals
    • pascals
    • megapascals
    • atmospheres

  7. Using the phase diagram for carbon in the article above:
    • What is the minimum temperature and pressure required to produce liquid carbon from gaseous carbon?
    • What is the maximum pressure at which graphite can exist?
    • What is the maximum temperature at which graphite can exist?
    • How many phases of carbon are present at 4500K and 0.01GPa?
    • What is the triple point for diamond?

Tuesday, July 27, 2010

Lithiated Graphite in Fusion Reactors

Nuclear fusion powers the stars and could be used to supply clean energy on Earth. A nuclear fusion plant would produce ten times more energy than a conventional nuclear fission reactor.

Scientists have been investigating the "plasma-material interface", the region in a fusion reactor where the inner lining cones into contact with the extreme heat of the plasma. A major challenge in finding the right coatings to line fusion reactors is that the material changes due to extreme conditions inside the reactors where temperatures can reach millions of degrees.

One such lining material uses lithium which is applied to the inner graphite wall of the reactor and diffuses into the graphite creating an entirely new material called lithiated graphite.
During a fusion reaction, some of the deuterium fuel atoms strike the inner walls of the reactor and either "pumped", causing them to bind with the lithiated graphite, or returned to the core and recycled back to the plasma.
The intense thermal energy inside the reactor causes tiny micro- and nano- scale features to "self-organise" on the surface of the lithiated graphite under normal plasma-surface interaction conditions. The surface only continues pumping for a few seconds before being compromised by damage induced by the extreme internal conditions.

Reference:
Purdue University (2010, July 27). Promise for nuclear fusion test reactors, findings show. ScienceDaily. Retrieved July 28, 2010, from http://www.sciencedaily.com­ /releases/2010/07/100727142415.htm


Study Questions
  1. Define nuclear fusion.
  2. Write an equation to represent a nuclear fusion reaction that might take place in a sun.
  3. Define nuclear fission.
  4. Write an equation to represent the nuclear fission of uranium-235.
  5. How are deuterium atoms similar to hydrogen atoms?
  6. How are deuterium atoms different to hydrogen atoms?
  7. Name another isotope of hydrogen and give its symbol.
  8. Name two allotropes of carbon.
  9. Discuss the ways in which the two allotropes are the same.
  10. Discuss the ways in which the two allotropes are different.
  11. Draw a structure for graphite.
  12. Use the drawing above to describe how lithiated graphite might be formed.
  13. Discuss how deuterium atoms in the fuel plasma could bind to lithiated graphite.