Name and Formula of Inorganic Molecules

Non-metallic elements combine to produce covalent compounds, that is, molecules in which the atoms are held together by covalent bonds.
But do you know how to name these molecules using IUPAC recommendations?
Can you write the formula for these molecules using IUPAC recommendations?

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Naming Binary Inorganic Non-metallic Compounds

Molecular Formula of Binary Inorganic Non-metallic Compounds

Formula for Hydrogen?

I admit it. I love TV game shows. Last Friday I watched one of my favourite shows while eating my (late) lunch. I was even moderately successful at answering some of the questions, until the Host asked The Chaser what the chemical formula for hydrogen was. This led to the following exchange:
Chaser: H
Host: Incorrect
Contestants: H one (we will assume they meant H₁)
Host: Incorrect. The correct answer is H two (we will assume he meant H₂)

So, who was right?

Let's take the Host's "correct" answer first.
The Earth's atmosphere contains small amounts of diatomic molecules of hydrogen gas. "Di" means two and "atomic" refers to atoms so hydrogen gas in the atmosphere is made up of molecules in which 2 atoms of hydrogen are bonded together. When we make hydrogen gas in the laboratory we are making these H₂ molecules. So it seems that the Host got it right ..... except ..... the question didn't ask for the formula of hydrogen gas found in the atmosphere!

So let's turn our attention to the Contestants' response.
Is H₁ a plausible chemical formula for hydrogen?
Not really. If there is only 1 atom of an element in the chemical formula, the "1" is trivial and not included in the formula, so H₁ is the same as H which was the Chaser's response!

So, was the Chaser right?
Is H a valid chemical formula for hydrogen?
Hydrogen is a strange atom. It has 1 proton in its nucleus, and 1 electron "orbiting" that nucleus. In fact, this 1 so-called "valence electron" is a feature common to all Group 1 metals (alkali metals), but other properties of hydrogen suggest it is more like a non-metal than a metal. This similarity to the Group 1 metals led to the prediction that it should be possible to create metallic hydrogen. This would be a solid in which the hydrogen atoms (protons in effect) would be held in a 3-dimensional array with delocalised electrons acting as the metallic bonds holding the array together. This metallic hydrogen would, in theory, be an excellent conductor, indeed it would be a "superconductor", which is why the race has been on to create it!

A chemical formula of a covalent molecule tells us how many atoms of each element are covalently bonded together, H₂ has 2 atoms of hydrogen with a covalent bond between them.
But the chemical formula for a 3-dimensional metallic array refers to the ratio of atoms of each element, if only 1 element is present in a metallic array, like that of sodium metal, then the chemical formula is just the symbol for the element, Na, in this case, or H if you are referring to metallic hydrogen.
So, H is a valid chemical formula for metallic hydrogen, if it exists.
But does metallic hydrogen exist?

In January 2017, researchers at Harvard University announced that they had produced metallic hydrogen in the laboratory using immense pressure. So metallic hydrogen, H, can exist.

Back to the game show.
The Host was right, H₂ is the chemical formula for gaseous hydrogen in the atmosphere.
The Chaser was right, H is the chemical formula for metallic hydrogen.
The Contestants were almost right: Chemists don't write H₁ they just write H.

There is a moral to this story.
Be careful when writing questions. The question should not be ambiguous unless you are prepared to accept multiple different answers that are correct.
Be even more careful when answering test and exam questions. If you need to make assumptions to answer the question you MUST state what those assumptions are when you write your answer.

Reference:

1. Ranga P. Dias, Isaac F. Silvera. Observation of the Wigner-Huntington Transition to Metallic Hydrogen. Science, 2017 DOI: 10.1126/science.aal1579

Tutorials Relevant to this Post

Periodic Table of the Elements
Elements and Compounds
Metals and Nonmetals
Molecular Formula

Naming Covalent Compounds
Empirical Formula and Molecular Formula
Trends in Group 1 Elements
Metallic Bonding

Suggested Study Questions

1. Use the Periodic Table of the Elements to find the chemical symbol for each of the following atoms:
• hydrogen
• helium
• carbon
• nitrogen
• oxygen
• chlorine
2. Write a molecular formula for each of the following diatomic gas molecules:
• hydrogen
• nitrogen
• oxygen
• chlorine
3. Give the number of atoms of each element present in the molecular formulae below:
• H₂O
• H₂O₂
• CO
• CO₂
• NH₃
• NO
• NO₂
• N₂O₂
4. Let M represent an atom of an element. Circle the elements below for which the molecular formula of the element at room temperature and pressure could be represented by M
• helium
• sodium
• oxygen
• iron
• gold
• neon
• chlorine
• nitrogen
• hydrogen
5. For the description of each molecule below, write the molecular formula
• one carbon atom and four hydrogen atoms
• one nitrogen atom and three chlorine atoms
• two nitrogen atoms and one oxygen atom
• one nitrogen atom and five oxygen atoms
• two chlorine atoms and two oxygen atoms
• one carbon atom, one hydrogen atom and three chlorine atoms
6. Given the name of each molecule below, write the molecular formula:
• hydrogen chloride
• carbon monoxide
• carbon dioxide
• sulfur dioxide
• sulfur trioxide
• sulfur dichloride
7. Consider the list of compounds with a possible molecular formulae below. Circle the incorrect formulae and justify your answer:
• water, 2HO
• carbon monoxide, C₁O₁
• hydrogen peroxide, H2O₂
• sulfur trioxide: SO₂
• ammonia, NH3
• hydrogen sulfide, H₂S
• carbon dioxide, C₂O
• sulfur dichloride, S₁Cl₂
8. From the list below, circle the elements that belong to Group 1 of the Periodic Table of the Elements:
• sodium
• helium
• oxygen
• lithium
• chlorine
• nitrogen
• carbon
• potassium
• calcium
9. Draw a table with the headings "metal" and "nonmetal". Place each of the following elements in the correct column:
• hydrogen
• helium
• calcium
• carbon
• nitrogen 
• potassium
• oxygen
• chlorine
• sodium
10. From the list below, circle the elements that would exist at room temperature and pressure as an array of "atoms" help together by delocalised electrons:
• hydrogen
• carbon
• sodium
• lithium
• nitrogen
• chlorine
• iron
• gold
• oxygen

Essential Elements

Most of the mass of the human body is made up of just 6 elements:

• 65% oxygen
• 18.5% carbon
• 9.5% hydrogen
• 3.2% nitrogen
• 1.5% calcium
• 1% phosphorus

Carbon and hydrogen are the building blocks making up organic (carbon) molecules, and so, since the human body is just an incredibly complicated organic chemical factory, it is no surprise that carbon and hydrogen make up such a huge amount of the mass of a human body. Oxygen is present in most of the biochemicals making up your body, while nitrogen is an essential component of proteins. Why is there so much phosphorus? Phosphorus and oxygen combine to make up the glue that holds your DNA together, no phosphorus, no DNA, no you! And calcium is ofcourse present in bones and teeth.
Then there are minor amounts of other elements such as potassium, sulfur, sodium, chlorine and magnesium which make up less than 1% of the remaining mass of the human body.

Some elements, like iron, are absolutely essential in order for the human body to survive, but are present in extremely minute amounts, for iron this is about 0.006%

H																		He
Li	Be												B	C	N	O	F	Ne
Na	Mg												Al	Si	P	S	Cl	Ar
K	Ca		Sc	Ti	V	Cr	Mn	Fe	Co	Ni	Cu	Zn	Ga	Ge	As	Se	Br	Kr
Rb	Sr		Y	Zr	Nb	Mo	Tc	Ru	Rh	Pd	Ag	Cd	In	Sn	Sb	Te	I	Xe
Cs	Ba	*	Lu	Hf	Ta	W	Re	Os	Ir	Pt	Au	Hg	Tl	Pb	Bi	Po	At	Rn
Fr	Ra	**	Lr	Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Uut	Fl	Uup	Lv	Uus	Uuo
		*	La	Ce	Pr	Nd	Pm	Sm	Eu	Gd	Tb	Dy	Ho	Er	Tm	Yb
		**	Ac	Th	Pa	U	Np	Pu	Am	Cm	Bk	Cf	Es	Fm	Md	No

Vanderbilt University Scientists have just found out that bromine is also essential.It appears that bromine is important to an enzyme that is used to make a particular type of sulfur-nitrogen bond within the collagen IV structure used to make the scaffold for cells.

Reference:
A. Scott McCall, Christopher F. Cummings, Gautam Bhave, Roberto Vanacore, Andrea Page-McCaw, Billy G. Hudson. Bromine Is an Essential Trace Element for Assembly of Collagen IV Scaffolds in Tissue Development and Architecture. Cell, 2014; 157 (6): 1380 DOI: 10.1016/j.cell.2014.05.009

Further Reading
Periodic Table
Metals and Non-metals

Percentage Composition
Mass-Mole Calculations 

Suggested Study Questions:

1.  Give the chemical symbol for each of the following elements:
   • oxygen
   • carbon
   • hydrogen
   • nitrogen
2. Give the name for each of the following elements:
   • Fe
   • Ca
   • P
   • K
   • Mg
3. Give the atomic number for each of the following elements
   • sulfur
   • sodium
   • iodine
   • Cl
   • F
   • Br
4. Make a table of the metals and non-metals named in the article above
5. Chris the Chemist has a mass of 90 kg. Calculate the mass, in kilograms, of each of the following elements in Chris' body
   • carbon
   • hydrogen
   • oxygen
   • nitrogen
6. Calculate the mass of iron in Chris' body in
   • kilograms
   • grams
   • milligrams
   • micrograms
7. Calculate the moles of each of the following elements found in Chris' body
   • carbon
   • hydrogen
   • oxygen
   • nitrogen
8. Do you think Scientists will one day claim that lead is an element essential for human life? Explain your answer.

Ancient Elements

Only about a dozen elements were known to the people living in ancient civilizations.

• Copper beads dating from about 6000 B.C. have been found in Turkey.

• A lead statuette found in an Egyptian temple dates from around 3800 B.C. and golden artefacts have also been found in ancient Egyptian tombs.

• Silver was used by the ancient Greeks and Romans to prevent infection, and was used as an early form of currency.

• There is evidence of the systematic production of iron in Turkey around 2000 B.C. for use in tools and weapons.

• Carbon, in the form of diamonds, was also known in the Ancient world, but, carbon in the form of charcoal was far more important to these early people because it could be used in the production of copper, tin, and therefore bronze (an alloy of copper and tin).

• Sulfur was also known to the Ancient Egyptians and Greeks, who used it as a medicine.

• The ancient Chinese, Indians and Egyptians also knew about mercury, using it in ointments and cosmetics.

• Before 1000 B.C., Indians were extracting zinc from its ores. Ornaments containing 80% or more of zinc have been found.

• During the Bronze Age (an earlier period than the Iron Age), arsenic was included in bronze to make the alloy harder. Ancient people understood that they could produce arsenic by heating certain substances (which we would now call arsenic sulfides and oxides).

• Antimony was used in cosmetics in the Ancient world, notably by the Egyptians who used it around their eyes (known as kohl).

• Chromium has been found in ancient Chinese artifacts. The weapons the Chinese Terracotta Army carry are coated in chromium oxide and date from around the 3rd century B.C.

In fact, these were really the only elements known  until the 17th century A.D.
Today we know of over a 100 elements.
Chemistry has come a long way in the last few hundred years!

Further Reading:
History of the Elements
Metal Extraction Concepts
Periodic Table
Metals and Non-metals
Pure Substances and Mixtures

Suggested Study Questions:

1.  Find each of the elements mentioned above on the Periodic Table.
2. Draw up a table of the name and chemical symbol for each of the elements mentioned above.
3. Draw up a table classifying each of these elements as metals, non-metals or semi-metals (metalloids).
4. Name a mixture mentioned in the article above.
5. Name a compound mentioned in the article above.
6. There are only 3 metallic elements that are not a "silvery" colour. One of these is cesium (or caesium), but if the sample of cesium is very pure it loses its golden colour. Name the other two non-silvery metallic elements.
7. Explain why you often find weapons like swords made of iron, but you never find functional weapons made of gold.
8. Explain why you find ornamental weapons made out of gold, but rarely out of zinc.
9. Ancient people could have produced mercury by heating cinnabar (mercury(II) sulfide). The cinnabar decomposes, producing liquid mercury and sulfur. Write a word equation for the decomposition of cinnabar.